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Mossbauer study of mechanically alloyed Fe57Cr31Co12

Identifieur interne : 000B30 ( Main/Exploration ); précédent : 000B29; suivant : 000B31

Mossbauer study of mechanically alloyed Fe57Cr31Co12

Auteurs : F.-Z. Bentayeb [Algérie] ; S. Alleg [Algérie] ; B. Bouzabata [Algérie] ; J. M. Greneche [France]

Source :

RBID : Pascal:02-0189687

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English descriptors

Abstract

Nanostructured powders of Fe57Cr31Co12 were prepared by mechanical alloying from elemental Fe, Cr and Co powders, using a planetary ball mill type Fritsch Pulverisette 7. The powders were characterized by X-ray diffraction and 57Fe Mossbauer spectrometry. A detailed analysis of the diffraction patterns reveals a decrease of the crystalline grain size as a function of milling time. For the first hours of milling, Mossbauer spectra are composed of a magnetic contribution and a single line. The paramagnetic component, whose relative area increases with milling time, can be attributed to paramagnetic Cr-rich clusters. The results are compared to those obtained on the same alloy prepared by conventional melting technique.


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<term>Mechanical alloying</term>
<term>Melting</term>
<term>Moessbauer effect</term>
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<term>Ternary alloys</term>
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<term>Effet Mössbauer</term>
<term>Alliage mécanique</term>
<term>Broyeur satellite</term>
<term>Broyeur boulet</term>
<term>Diffraction RX</term>
<term>Grosseur grain</term>
<term>Dépendance temps</term>
<term>Fusion</term>
<term>Transformation phase</term>
<term>Nanostructure</term>
<term>Poudre</term>
<term>Fer alliage</term>
<term>Matériau paramagnétique</term>
<term>Chrome alliage</term>
<term>Cobalt alliage</term>
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<div type="abstract" xml:lang="en">Nanostructured powders of Fe
<sub>57</sub>
Cr
<sub>31</sub>
Co
<sub>12</sub>
were prepared by mechanical alloying from elemental Fe, Cr and Co powders, using a planetary ball mill type Fritsch Pulverisette 7. The powders were characterized by X-ray diffraction and
<sup>57</sup>
Fe Mossbauer spectrometry. A detailed analysis of the diffraction patterns reveals a decrease of the crystalline grain size as a function of milling time. For the first hours of milling, Mossbauer spectra are composed of a magnetic contribution and a single line. The paramagnetic component, whose relative area increases with milling time, can be attributed to paramagnetic Cr-rich clusters. The results are compared to those obtained on the same alloy prepared by conventional melting technique.</div>
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